{"id":1663,"date":"2025-04-04T11:42:57","date_gmt":"2025-04-04T11:42:57","guid":{"rendered":"https:\/\/catalysis.chem.uoi.gr\/?p=1663"},"modified":"2025-04-04T11:42:57","modified_gmt":"2025-04-04T11:42:57","slug":"highly-efficient-reusable-silicaiminophosphine-feii-hybrids-for-hydrogen-production-via-formic-acid-and-formaldehyde-dehydrogenation","status":"publish","type":"post","link":"https:\/\/catalysis.chem.uoi.gr\/index.php\/2025\/04\/04\/highly-efficient-reusable-silicaiminophosphine-feii-hybrids-for-hydrogen-production-via-formic-acid-and-formaldehyde-dehydrogenation\/","title":{"rendered":"Highly-Efficient Reusable [Silica@Iminophosphine-FeII] Hybrids for Hydrogen Production via Formic Acid and Formaldehyde Dehydrogenation"},"content":{"rendered":"\n\n\n<figure class=\"wp-block-image size-large\"><a href=\"https:\/\/catalysis.chem.uoi.gr\/wp-content\/uploads\/2025\/04\/chem202404440-toc-0001-m.jpg\"><img decoding=\"async\" loading=\"lazy\" width=\"1024\" height=\"672\" src=\"https:\/\/catalysis.chem.uoi.gr\/wp-content\/uploads\/2025\/04\/chem202404440-toc-0001-m-1024x672.jpg\" alt=\"\" class=\"wp-image-1664\" srcset=\"https:\/\/catalysis.chem.uoi.gr\/wp-content\/uploads\/2025\/04\/chem202404440-toc-0001-m-1024x672.jpg 1024w, https:\/\/catalysis.chem.uoi.gr\/wp-content\/uploads\/2025\/04\/chem202404440-toc-0001-m-300x197.jpg 300w, https:\/\/catalysis.chem.uoi.gr\/wp-content\/uploads\/2025\/04\/chem202404440-toc-0001-m-768x504.jpg 768w, https:\/\/catalysis.chem.uoi.gr\/wp-content\/uploads\/2025\/04\/chem202404440-toc-0001-m.jpg 1308w\" sizes=\"(max-width: 1024px) 100vw, 1024px\" \/><\/a><\/figure>\n\n\n\n<p>Konstantina Gravvani, Maria Solakidou, Maria Louloudi<\/p>\n\n\n\n<p><a href=\"https:\/\/doi.org\/10.1002\/chem.202404440\">https:\/\/doi.org\/10.1002\/chem.202404440<\/a><\/p>\n\n\n\n<p>This study presents the design and application of two Fe(II)-based hybrid catalysts, [SiO\u2082@benzNP-Fe<sup>II<\/sup>] and [SiO\u2082@benzNHP-Fe<sup>II<\/sup>], for efficient hydrogen (H\u2082) production via formic acid (HCOOH) and formaldehyde (HCHO) dehydrogenation. The reduction of Schiff base ligands to incorporate N\u2212H groups significantly enhances efficiency, stability, and reusability. Achieving &gt;80,000 total turnover numbers (TONs), the results highlight their potential for sustainable energy solutions.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Konstantina Gravvani, Maria Solakidou, Maria Louloudi https:\/\/doi.org\/10.1002\/chem.202404440 This study presents the design and application of two Fe(II)-based hybrid catalysts, [SiO\u2082@benzNP-FeII] and [SiO\u2082@benzNHP-FeII], for efficient hydrogen (H\u2082) production via formic acid (HCOOH) and formaldehyde (HCHO) dehydrogenation. The reduction of Schiff base ligands to incorporate N\u2212H groups significantly enhances efficiency, stability, and reusability. Achieving &gt;80,000 total turnover &hellip; <a href=\"https:\/\/catalysis.chem.uoi.gr\/index.php\/2025\/04\/04\/highly-efficient-reusable-silicaiminophosphine-feii-hybrids-for-hydrogen-production-via-formic-acid-and-formaldehyde-dehydrogenation\/\" class=\"more-link\">Continue reading <span class=\"screen-reader-text\">Highly-Efficient Reusable [Silica@Iminophosphine-FeII] Hybrids for Hydrogen Production via Formic Acid and Formaldehyde Dehydrogenation<\/span> <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":1,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":[],"categories":[1],"tags":[],"_links":{"self":[{"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/posts\/1663"}],"collection":[{"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/users\/1"}],"replies":[{"embeddable":true,"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/comments?post=1663"}],"version-history":[{"count":1,"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/posts\/1663\/revisions"}],"predecessor-version":[{"id":1665,"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/posts\/1663\/revisions\/1665"}],"wp:attachment":[{"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/media?parent=1663"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/categories?post=1663"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/catalysis.chem.uoi.gr\/index.php\/wp-json\/wp\/v2\/tags?post=1663"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}